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Liz Hurley will co-host a special celebration gala for West End musical Chicago at the Cambridge Theatre on 5 December.
Andrew Lloyd Webber and Oscar winner Julian Fellowes will join Liz, 42, to present the event.
Former stars of the show including Denise Van Outen, Jennifer Ellison and Duncan James have also been roped in to raise cash for Breast Cancer Haven and the Breast Health Institute.
Chicago opened in 1997 and has played to over 4.5 million people.
The latest well-known name to join the cast is Kelly Osbourne who is playing Mama Morton.